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SECOND LAW OF THERMODYNAMICS

Heat Engine & Entropy Interactive Simulator

ηactual ≤ ηCarnot ΔStotal ≥ 0

⚡ SECOND LAW OF THERMODYNAMICS CONSTRAINTS

  • Heat flows naturally from Hot Reservoir to Cold Reservoir (TH > TC).
  • No heat engine can convert 100% of supplied heat into useful mechanical work (η < 100%).
  • Some heat QC MUST be rejected to the cold sink: QH = W + QC.
  • Entropy generation of the universe is strictly non-negative (ΔStotal ≥ 0).
Actual Efficiency (η)
62.5%
η = W / QH
Carnot Max Efficiency
62.5%
ηmax = 1 − TC/TH
Work Output (W)
625 J
Mechanical Output
Entropy Generation
0.000 J/K
ΔStotal per cycle
🏭 HEAT ENGINE & FLYWHEEL ANIMATION
➡️ ENERGY FLOW DIAGRAM (QH = QC + W)
📈 TEMPERATURE–ENTROPY (T–S) DIAGRAM
📊 ENTROPY MONITOR (ΔShot + ΔScold)
Recorded Experimental Trials
Trial Mode TH (K) TC (K) QH (J) QC (J) W (J) ηactual ηCarnot ΔSgen (J/K)

🔥 Kelvin-Planck Statement

It is impossible for any device that operates on a thermodynamic cycle to receive heat from a single thermal reservoir and deliver a net amount of work to its surroundings.

Wnet ≤ QH (1 − TC / TH)

❄️ Clausius Statement

It is impossible to construct a device that operates in a cycle and produces no effect other than the transfer of heat from a lower-temperature body to a higher-temperature body without work input.

Heat flows naturally: Hot → Cold

🌀 Entropy & Irreversibility

For any process, the total entropy change of the universe must be non-negative. In reversible processes ΔStotal = 0, while in real irreversible processes friction and heat losses cause ΔStotal > 0.

ΔSgen = −QH/TH + QC/TC ≥ 0

🚀 Real-World Applications

Steam Turbines (Rankine cycle), Gas Turbines (Brayton cycle), Internal Combustion Engines (Otto/Diesel cycle), HVAC & Heat Pumps, Cryogenic Cooling, and Thermal Power Stations.

Max Limit = Carnot Efficiency

Knowledge Check: 2nd Law of Thermodynamics